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Tuesday, October 19, 2010

Biofuel

DuPont scientist Max Li developing new biofuels in his state-of-the-art fermentation lab at the …
[Credit: PRNewsFoto/DuPont/AP Images]Ethanol gas fuel pump delivering the E85 mixture to an automobile in Washington state, U.S.
[Credit: © Carolina K. Smith, M.D./Shutterstock.com] biofuel, any fuel that is derived from biomass that is, plant material or animal waste. Since such feedstock material can be replenished readily, biofuel is considered to be a source of renewable energy, unlike fossil fuels such as petroleum, coal, and natural gas. Biofuel is perceived by its advocates as a cost-effective and environmentally benign alternative to petroleum and other fossil fuels, particularly within the context of rising petroleum prices and increased concern over the contributions made by fossil fuels to global warming. Many critics express concerns about the scope of the expansion of certain biofuels because of the economic and environmental costs associated with the refining process and the removal of vast areas of arable land from food production.

Types of biofuels

A worker pumping palm-oil-derived biodiesel fuel into a tanker at a plant in Ipoh, Malaysia.
[Credit: Zainal Abd Halim—Reuters/Landov]Some long-exploited biofuels, such as wood, can be used directly as a raw material that is burned to produce heat. The heat, in turn, can be used to run generators in a power plant to produce electricity. A number of existing power facilities burn grass, wood, or other kinds of biomass.

An ethanol production plant in South Dakota, U.S.
[Credit: © Jim Parkin/Shutterstock.com]Liquid biofuels are of particular interest because of the vast infrastructure already in place to use them, especially for transportation. The liquid biofuel in greatest production is ethanol (ethyl alcohol), which is made by fermenting starch or sugar. Brazil and the United States are among the leading producers of ethanol. In the United States, ethanol biofuel is made primarily from corn (maize) grain, and it is typically blended with gasoline to produce “gasohol,” a fuel that is 10 percent ethanol. In Brazil, ethanol biofuel is made primarily from sugarcane, and it is commonly used as a 100-percent-ethanol fuel or in gasoline blends containing 85 percent ethanol.

A cutting machine on a plantation in southeastern Brazil harvesting sugarcane, the primary source …
[Credit: Andre Penner/AP]The second most common liquid biofuel is biodiesel, which is made primarily from oily plants (such as the soybean or oil palm) and to a lesser extent from other oily sources (such as waste cooking fat from restaurant deep-frying). Biodiesel, which has found greatest acceptance in Europe, is used in diesel engines and usually blended with petroleum diesel fuel in various percentages.

Other biofuels include methane gas which can be derived from the decomposition of biomass in the absence of oxygen and methanol, butanol, and dimethyl ether which are in development.
At present, much focus is on the development of methods to produce ethanol from biomass that possesses a high cellulose content. This cellulosic ethanol could be produced from abundant low-value material, including wood chips, grasses, crop residues, and municipal waste. The mix of commercially used biofuels will undoubtedly shift as these fuels are developed, but the range of possibilities presently known could furnish power for transportation, heating, cooling, and electricity.

Economic and environmental considerations

Unloading kernels of corn (maize) from a truck into a delivery chute at a bioethanol plant in …
[Credit: Jason Reed—Reuters/Landov]In evaluating the economic benefits of biofuels, the energy required to produce them has to be taken into account. For example, the process of growing corn to produce ethanol consumes fossil fuels in farming equipment, in fertilizer manufacturing, in corn transportation, and in ethanol distillation. In this respect ethanol made from corn represents a relatively small energy gain; the energy gain from sugarcane is greater and that from cellulosic ethanol could be even greater.

Biofuels also supply environmental benefits but, depending on how they are manufactured, can also have serious environmental drawbacks. As a renewable energy source, plant-based biofuels in principle make little net contribution to global warming and climate change; the carbon dioxide (a major greenhouse gas) that enters the air during combustion will have been removed from the air earlier as growing plants engage in photosynthesis. Such a material is said to be “carbon neutral.” In practice, however, the industrial production of agricultural biofuels can result in additional emissions of greenhouse gases that may offset the benefits of using a renewable fuel. These emissions include carbon dioxide from the burning of fossil fuels during the production process and nitrous oxide from soil that has been treated with nitrogen fertilizer. In this regard, cellulosic biomass is considered to be more beneficial.

Land use is also a major factor in evaluating the benefits of biofuels. Corn and soybeans are important foods, and their use in producing fuel can therefore affect the economics of food price and availability. By 2007 about one-fifth of the corn output in the United States was allocated to the production of biofuel, and one study showed that even if all U.S. corn land was used to produce ethanol, it could replace just 12 percent of gasoline consumption. In addition, crops grown for biofuel can compete for the world’s natural habitats. For example, emphasis on ethanol derived from corn is shifting grasslands and brushlands to corn monocultures, and emphasis on biodiesel is bringing down ancient tropical forests to make way for palm plantations. Loss of natural habitat can change the hydrology, increase erosion, and generally reduce biodiversity of wildlife areas. The clearing of land can also result in the sudden release of a large amount of carbon dioxide as the plant matter that it contains is burned or allowed to decay.

Some of the disadvantages of biofuels apply mainly to low-diversity biofuel sources—corn, soybeans, sugarcane, oil palms which are traditional agricultural crops. One alternative involves the use of highly diverse mixtures of species, with the North American tallgrass prairie as a specific example. Converting degraded agricultural land that is out of production to such high-diversity biofuel sources could increase wildlife area, reduce erosion, cleanse waterborne pollutants, store carbon dioxide from the air as carbon compounds in the soil, and ultimately restore fertility to degraded lands. Such biofuels could be burned directly to generate electricity or converted to liquid fuels as technologies develop.

The proper way to grow biofuels to serve all needs simultaneously will continue to be a matter of much experimentation and debate, but the fast growth in biofuel production will likely continue. In the European Union, for example, biofuels are planned to account for 5.75 percent of transport fuels by 2010, and 10 percent of European vehicles are expected to run exclusively on biofuels by 2020. In the United States the Energy Independence and Security Act of 2007 mandated the use of 136 billion litres (36 billion gallons) of biofuels annually by 2020, more than a sixfold increase over 2006 production levels. The legislation also requires, with certain stipulations, that 79 billion litres (21 billion gallons) of the total amount be biofuels other than corn-derived ethanol, and it continued certain government subsidies and tax incentives for biofuel production. In addition, the technology for producing cellulosic ethanol is being developed at a number of pilot plants in the United States.

One distinctive promise of biofuels is that, in combination with an emerging technology called carbon capture and storage, the process of producing and using biofuels may be capable of perpetually removing carbon dioxide from the atmosphere. Under this vision, biofuel crops would remove carbon dioxide from the air as they grow, and energy facilities would capture the carbon dioxide given off as biofuels are burned to generate power. Captured carbon dioxide could be sequestered (stored) in long-term repositories such as geologic formations beneath the land, in sediments of the deep ocean, or conceivably as solids such as carbonates.

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